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PRODID:https://murmitoyen.com/events/vanille/udem/
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DTSTAMP:20260414T222042
DTSTART:20141210T110000
SEQUENCE:0
TRANSP:OPAQUE
DTEND:20141210T123000
URL:https://murmitoyen.com/events/vanille/udem/detail/453637
LOCATION:Université de Montréal - Pavillon Claire-McNicoll\, 2900\, chemi
 n de la Tour\, Montréal\, QC\, Canada\, H3T 1J6
SUMMARY:Conférence CCVC avec le Professeur Matthew Sigman (Utah)
DESCRIPTION:Titre : Palladium-Catalyzed Alkene Functionalization Reactions 
 for Synthesis.Endroit : Pavillon Claire-McNicoll\, salle Z-317 à 11 hHôt
 e : Professeur André CharetteLa conférence sera prononcée en anglais pa
 r le professeur Matthew Sigman du Département de chimie de l'University o
 f Utah. Elle est commanditée par le Centre en chimie verte et catalyse (
 CCVC)Résumé : Critical to the development of catalysts with practical po
 tential in synthetic chemistry is a fundamental understanding of the mecha
 nistic features which lead to a robust and selective catalytic system.  W
 ithin this regard\, our group has focused on the development of new pallad
 ium catalysts for various oxidation and cross-coupling reactions wherein m
 echanistic analysis has played a vital role in catalyst and reaction desig
 n.  This presentation will focus on our recent efforts to design new reac
 tions with a particular emphasis of redox-relay enantioselective Heck reac
 tions\,wherein exquisite control of migratory insertion and β-hydride eli
 mination is required for a successful outcome.Références : a) Werner\, E
 . W.\, Mei\, T.-S.\, Burckle\, A. J.\, Sigman\, M. S. Science 2012\, 338\,
  1455.  b) Mei\, T.-S.\, Werner\, E. W.\, Burckle\, A. J.\, Sigman\, M. S
 . J. Am. Chem. Soc. 2013\, 135\, 6830. c) Mei\, T-S.\; Patel. H. H. Sigman
 \, M. S. Nature 2014\, 508\, 340. d) Xu\, L.\; Hilton\, M. J.\; Zhang\, X.
 \; Norrby\, P.-O.\; Wu\, Y.-D.\; Sigman\, M. S.\; Wiest\, O. J. Am. Chem. 
 Soc. 2014\, 136\, 1960.Information supplémentaireAnnonce PDF de la confé
 rence
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